“Pity sex happens when people have sex with other people because they feel sorry for them. Pity (or mercy) sex is an experience in which a woman (or a man) is not particularly attracted to someone who is in love with her and wishes to have sex with her; she sleeps with him because she feels sorry for him. Like a one-night stand, pity sex is usually an isolated occurrence; unlike a one-night stand, pity sex has an altruistic element, intended to give pleasure to the other person but not to the one who pities—after all, pity is not a pleasant emotion. Many people (women probably more so) may have sex because they think they “should" rather than because they actually want to. This can be a kind of guilt-induced sex. (See here.)

Charity sex is common in ongoing relationships that have lasted for a while and usually occurs in an effort to maintain or enhance the relationship. It can be regarded as a kind of investment in the relationship; like other investments, you might not see the benefits immediately, but you increase the prospects of reaping benefits in the future. Charity sex typically occurs in a situation of profound love, in which the sexual aspect has significantly diminished over time. In charity sex, you love your partner, but don't feel like having sex with him or her. It might not be enjoyable, but it typically does not involve suffering. In pity sex, the pitying partner does not want to have sex with the one she pities because she is not physically attracted to him. In charity sex, you usually find your partner attractive and generally enjoy having sex with him, but at this specific time you do not feel like having sex. Nevertheless, you consent, as you believe your partner wishes it or will benefit from it—for instance, because he is feeling somewhat low and sex will improve his mood.

Peace-inducing sex is instrumental sex intended to maintain industrial peace in the relationship. It has elements of both pity and charity sex. Like charity sex, it is a long-term strategy intended to maintain the relationship. Whereas charity sex aims to promote the relationship, peace-inducing sex aims to prevent the deterioration of the relationship. Like pity sex, the agent does not enjoy the sex and often suffers while having it. Peace-inducing sex can be very painful when both sides lack any positive affective attitude. Consider the following description by a woman (who has a lover): "Last night I had sex with my husband, but he did not actually touch me—just penetrated me. I was so sad, I felt like crying." -Psychology Today. “Other Scenarios

Drunken sex is another type of sex that in normal circumstances would not be desirable, but the difference here is that whereas in pity sex the pitying person does not enjoy the sexual activity, in drunken sex he or she might. The conflict in pity sex is between what you do not want and what the other person does want; in drunken sex, the conflict is between what you would not want in normal circumstances and what you want when you are intoxicated.
In the case of expedient sex, people may have sex with someone, not out of love or pity, but in order to derive some material benefit, such as money or status. The classic scenario would be an attractive young woman and a much older, wealthier man. In this case, the altruistic element is replaced by the element of greed.
In the case of sexual friendship (or "friends with benefits"), where the connection between the two partners is based on sex and perhaps casual friendship, mutual pleasure can be derived. But since such a relationship does not involve love, it is more superficial and less meaningful. Sometimes, however, people greatly enjoy superficial experiences, particularly when they do not impose many obligations on either side.” -Psychology Today.

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